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感谢亲爱的读者、作者朋友们一直以来对 Wiley 化学期刊的支持与关注,为了进一步拉近期刊与广大中国科研工作者的距离,致敬并鼓励来自中国的优秀研究成果,Wiley旗下7本化学期刊特别联合发起本次“Best Paper Award”(2025)线上评选活动,希望以此让更多优秀的中国研究成果被看见、被讨论、被启发。发起本次活动的期刊包括:

  • Advanced Synthesis & Catalysis

    作为有机合成与催化领域的领军期刊之一,ADSC 致力于发表高效、创新且具有实际应用潜力的合成方法与催化体系。

  • Chemistry – A European Journal

    作为欧洲化学学会历时超过30年的旗舰期刊,ChemEurJ 涵盖化学全领域,以高质量、高包容性著称,是展示跨学科前沿成果的理想平台。

  • ChemSusChem

    聚焦可持续化学与绿色能源,ChemSusChem 关注生物质转化、光/电催化、二氧化碳利用等热点方向,助力碳中和目标。

  • ChemistryEurope

    作为一本面向全球的跨学科化学期刊,ChemistryEurope 强调欧洲视角下的国际合作,鼓励原创性与科学开放。

  • ChemElectroChem

    专注电化学领域,涵盖电池、超级电容器、电催化、腐蚀与电分析等方向,是电化学研究者交流前沿成果的重要阵地。

  • ChemistryOpen

    作为一本完全开放获取期刊,ChemistryOpen 为化学各领域的研究者提供快速、公正、可见度高的发表平台。

  • Chemistry-Methods

    作为一本完全开放获取期刊,聚焦化学方法学创新,涵盖实验技术、数据分析、自动化与仪器开发等方向,推动化学研究的可重复性与可复用性。

每一本期刊的主编已从 2025 年发表的文章中 遴选出5 篇由中国(以中国为通讯作者单位)科研团队完成的优秀论文,作为本次评奖的候选论文。这些论文代表了期刊在过去一年中最具启发性和代表性的工作,值得被更多读者了解和引用。

现在,我们诚邀您为最打动您的那篇论文投上一票!

为什么您的投票很重要?

每一篇优秀论文的背后,都是一个研究团队的努力与坚持。您的投票不仅是对作者工作的认可,也帮助我们将那些对读者最有启发、最具实用价值或创新精神的研究推向台前。我们希望通过这次评选,能够让优秀的科研成果得到更多同行关注,也使期刊与读者之间的距离更近一步。

投票时间

2026 年 5 月 21 日 – 2026 年 6 月 15 日

奖项设置

  • 最佳论文奖(1 篇/刊):团队将获得价值488元的华为耳机一份,证书一份;

  • 优秀论文奖(4 篇/刊):团队将获得 优秀论文证书一份;

  • 读者参与奖(共计20份):参与投票的读者将有机会获得价值 56元的绿联拓展坞一份,感谢您的热情参与!

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投票方式

请扫描下方二维码或点击链接进入投票页面,选择您支持的论文并提交。

https://uao.so/pct0db056b

*每本期刊的论文为单选投票。您可以为单本期刊或多本期刊进行投票。感谢每一位愿意花时间阅读和投票的你。也祝贺所有入选论文的作者,感谢你们为化学研究带来的灵感与进步。

参选文章信息

Advanced Synthesis & Catalysis

1

Photo-Induced Oxidative C−H Esterification of Quinoxalinones with Arylaldehydes under Mild Conditions

作者:Kai Zheng, Zhaoyang Wang, Yacong Wang, Chao Chen, Chao Shen

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The first example for photo-induced oxidative C−H esterification of quinoxalinones with arylaldehydes under benign conditions has been reported. This method is distinguished by its capacity to accommodate a diverse array of quinoxalinones and arylaldehydes, culminating in the synthesis of the corresponding esters with moderate to good yields. The protocol is lauded for its environmental benignity, eschewing the need for hazardous transition metals and costly photocatalysts, and relies solely on hydrogen peroxide (H2O2) as the oxidant. Moreover, the scalability of the synthesis and the derivative transformations of the products have been demonstrated, underscoring its practical utility in organic synthesis.

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原文链接:http://dx.doi.org/10.1002/adsc.202500018

2

Photoredox-Catalyzed Radical Alkylation/Cyclization of Isocyanides with Organoboron Reagents for Diversified Synthesis of N-Heteroaromatics

作者:Shichao Yang, Xiangwen Tan, Dan Liu, Huanfeng Jiang, Wanqing Wu

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The utility of alkyl boronic acids as alkyl radical precursors in photoredox-catalyzed reactions has been limited due to their low reactivity. A photoredox-catalyzed radical alkylation/cyclization of functional arylisocyanides with alkyl boronic acids is reported herein. This strategy allows the formation of alkyl radicals from boronic acids containing primary, secondary, and tertiary alkyl groups, which are subsequently transformed into structurally diverse alkylated products, including quinoxalines, phenanthridines, benzothiazoles, benzoselenazoles and quinolines. This transformation features readily available radical precursors and a broad substrate scope. The reaction mechanism is investigated by fluorescence quenching, light on/off, and cyclic voltammograms (CV) experiments. The combination of alkyl boronic acids with DBU may lead to the formation of the alkyl radical via a single electron transfer (SET) process, while the arylisocyanides may undergo an energy transfer (EnT) process with photocatalyst under visible light to generate the carbon radical or act as a radical acceptor to react with the alkyl radical.

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原文链接:https://doi.org/10.1002/adsc.202500031

3

Rh(III)-Catalyzed C−H Cyclization of 2-Arylbenzimidazoles with CF3-Imidoyl Sulfoxonium Ylides and Further Sc(III)-Catalyzed Deaminative Hydroxylation

作者:Juting Liao, Ruirui Zhai, Xiaoyang Gao, Hongliang Wu, Dulin Kong, Shuojin Wang, Xun Chen

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An efficient Rh(III)-catalyzed C−H bond activation/cyclization of 2-arylbenzimidazoles with CF3-imidoyl sulfoxonium ylides has been achieved, yielding diverse CF3− and amino-disubstituted 5,6-dihydrobenzoimidazo[2,1-a]isoquinolines, which could undergo a deaminative hydroxylation to access CF3− and hydroxy-disubstituted 5,6-dihydrobenzoimidazo[2,1-a]isoquinolines catalyzed by Sc(OTf)3. This developed strategy features easily available starting materials, broad substrate scope, good scalability and high efficiency. Moreover, the antitumor activities of selected products against some human cancer cell lines were also investigated, and the results indicated that several products show antiproliferative activities.

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原文链接:http://dx.doi.org/10.1002/adsc.202401220

4

Electrochemical Dual Trifluoromethylation/Cyclization of 2-Aryl-N-Acryloyl Indoles Enabling Assembly of Indole[2,1-a]isoquinolines

作者:Haibo Mei, Yucheng Zhang, Jiang Liu, Jorge Escorihuela, Loránd Kiss, Jianlin Han

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An electrochemical cascade radical cyclization of 2-aryl-N-acryloyl indoles with sodium trifluoromethanesulfinate as a coupling partner has been explored, which afforded the unexpected bis-trifluoromethylated indole[2,1-a]isoquinolines as products. Experimental results and DFT calculations disclose that this reaction involves trifluoromethylation-triggered cyclization and the second trifluoromethylation as the key steps. This strategy does not need any transition-metal catalysts or oxidants with a readily available trifluoromethylating reagent enabling facile synthesis of bis-trifluoromethylated indole-fused tricycles.

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原文链接:http://dx.doi.org/10.1002/adsc.202401225

5

Heterogeneous Copper Single-Atom Catalyzed Three-Component Radical Difunctionalization of Alkenes

作者:Kaijian Liu, Yumin Ding, Jie Li, Zhuobin Yu, Jiarui Guo, Yantao Zhou, Kejun Luo, Jinhua Ou

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The Cu single-atom catalyst Cu1@NC enables efficient three-component alkene difunctionalization with quinoxalinones and polyhalogenated alkanes. This versatile protocol features broad substrate scope, excellent catalyst recyclability, and successful late-stage modification of complex bioactive molecules.

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原文链接:http://dx.doi.org/10.1002/adsc.70257

Chemistry – A European Journal

1

Simultaneous Construction of Axial and Central Stereogenicity by Cobalt-Catalyzed Stereoconvergent Reductive Coupling of Heterobiaryl Triflates and Aldehydes

作者:Chuiyi Lin, Xiang Xu, Prof. Dr. Qinglei Chong, Prof. Dr. Fanke Meng

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A new approach for highly diastereo- and enantioselective reductive coupling of racemic heterobiaryl triflates and aldehydes promoted by a readily available cobalt-based catalyst was developed. This protocol represents the first example of incorporating a chiral fragment onto the heterobiaryl core, enabling simultaneous construction of central and axial stereogenicity.

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原文链接:https://doi.org/10.1002/chem.202500248

2

Vinylene-Linked Fully Conjugated 3D Covalent Organic Polymers for Photocatalytic H2O2 Production

作者:Rui Zhang, Ms. Wenjing Ning, Mr. Ruiyang Zhang, Prof. Yan Huang, Prof. Xianren Zhang, Prof. Dapeng Cao, Prof. Shitao Wang

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Two novel vinylene-linked fully conjugated 3D covalent organic polymers (COPs) were synthesized. Both materials showed efficient photocatalytic hydrogen peroxide (H2O2) generation, where the thiophene-enriched COP outperformed than that of the benzene-modified counterpart, highlighting the critical role of thiophene units in enhancing catalytic activity.

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原文链接:https://doi.org/10.1002/chem.202501480

3

Spatial Confinement of Pd Nanoclusters in Pyrene-Based Covalent Organic Frameworks for Boosting Photocatalytic CO2 Reduction

作者:Yuling Lin, Xiaofang Lai, Guiting Huang, Jianhui Luo, Qiaoshan Chen, Guocheng Huang, Jinhong Bi

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COFs rich in N and S sites were utilized to anchor Pd ions and grow in situ into Pd nanoclusters. This enabled the IEF enhancement to drive the directional migration of photogenerated electrons and promote carrier separation. Meanwhile, the introduced Pd NCs act as active sites for CO2 adsorption and activation, realizing the efficiency enhancement of CO2 conversion to CO under visible light.

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原文链接:https://doi.org/10.1002/chem.202500766

4

A Parameter-Driven Approach to Modulating Chemical Composition in Prussian Blue Analogues Cathodes for Sodium-Ion Batteries

作者:Dr. Shamshad Ali., Cheng Ruan., Dr. Jicheng Jiang, Dr. Donghuang Wang, Dr. Xin Wang, Zaifang Yuan, Prof. Jingze Li, Prof. Yongqi Zhang, Prof. Aijun Zhou

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This study explores electroneutrality′s role in synthesizing sodium-based Prussian Blue Analogues (PBAs), focusing on Na+ ion diffusion and its effect on crystal structure. It examines how temperature, viscosity, and stirring speed influence Na+ incorporation, vacancies, and water content, offering insights for optimizing PBAs in energy storage.

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原文链接:https://doi.org/10.1002/chem.202404726

5

Direct Recycling of Cathode Materials from Spent Lithium-Ion Batteries: Principles, Strategies, and Perspectives

作者:Sihan Li, Zhan Wu, Miaoquan Zhang, Jianping Xu, Zheyu Jin, Yongping Gan, Zhihong Xu, Qingli Wang, Wenkui Zhang, Yang Xia, Xinping He, Jun Zhang

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This paper reviews the direct recycling methods for cathode materials derived from spent lithium-ion batteries. The focus includes the pretreatment processes involved in direct recycling, the degradation mechanisms of various cathode materials, and their corresponding regeneration strategies. Additionally, the future developments and prospects of cathode recycling for lithium-ion batteries are also discussed.

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原文链接:https://doi.org/10.1002/chem.202404461

ChemSusChem

1

Adjusting the Ratio of Oxidation States in a CuO@Cu2O for the Optimization of Electrocatalytic CO2 Conversion to Ethylene

作者:Jun Lu, Yanhan Ren, Liang Wang, Lie Zou, Jing Liang, Xiaolong Liang, Yan Gao, Fei Li, Junfeng Gao, Andreas Terfort, Jinxuan Liu

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By controlling the growth of CuO nanosheets on Cu₂O, the Cu2+/Cu+ ratio is precisely adjusted, enabling the efficient conversion of CO₂ to ethylene through interfacial effects.

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原文链接:https://doi.org/10.1002/cssc.202401963

2

Oxidation of 5-Hydroxymethylfurfural over ZnIn2S4/Ti3C2Tx

作者:Xiaoping Wang, Bowen Yang, Haoye Wang, Haixin Guo, Richard Lee Smith Jr, Yaqiong Su, Xinhua Qi

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Sulfur vacancy-enriched ZIS/MXene photocatalyst synthesized via self-assembly. Vs-ZIS-8/MX-6 achieves 87.3% HMF conversion and 72.9% DFF selectivity. An enhanced built-in electric field was constructed through the formation of a Schottky heterojunction between the two components. Extended X-ray absorption fine structure (EXAFS) spectroscopy results confirmed the formation of Zn-O coordination bonds at the interface of vacancy-enriched ZIS (Vs-ZIS) and MXene.

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原文链接:https://doi.org/10.1002/cssc.202501504

3

Highly-Efficient Recycling of Poly(ethylene terephthalate)/Polyethylene Film through Low-Temperature Methanolysis Catalyzed by Nonmetallic Deep Eutectic Solvent

作者:Xiashi Wang, Xin Wei, Jingwen Qiu, Weizhong Zheng, Weizhen Sun, Ling Zhao

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Facing the challenge of recycling multilayer plastic waste, a sustainable chemical process has been developed. Using a nonmetallic deep eutectic solvent, poly(ethylene terephthalate) (PET) is selectively depolymerized via methanolysis under mild conditions into dimethyl terephthalate (DMT, 97.1% yield) and ethylene glycol (EG). Meanwhile, the polyethylene (PE) layer remains intact. A novel two-step solid–liquid separation efficiently recovers pure PE, DMT, and EG, while the DES catalyst is successfully recycled. This work provides a green and scalable closed-loop solution for upcycling multilayer packaging materials.

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原文链接:https://doi.org/10.1002/cssc.202501863

4

Upcycling Polyoxymethylene via H2O2-Mediated Selective Oxidation

作者:Mugeng Chen, Kaizhi Wang, Zehui Sun, Wendi Guo, Chen Chen, Jiachen Fei, Ting Yang, Heyong He, Yongmei Liu, Yong Cao

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A sustainable methodology is reported for the mild upcycling of polyoxymethylene (POM) into formic acid using H2O2 as an oxidizing agent with microporous H-Beta zeolite. This approach enables simultaneous POM depolymerization and H2O2 activation, enhanced by 1,1,1,3,3,3-hexafluoroisopropanol. This effective conversion of waste POM into valuable formic acid addresses recycling challenges and promotes sustainable plastic waste management, contributing to a circular economy.

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原文链接:https://doi.org/10.1002/cssc.202500179

5

Benzene Ring Engineering of Graphitic Carbon Nitride for Enhanced Photocatalytic Dye Degradation and Hydrogen Production from Water Splitting

作者:Yongbo Fan, Lin Lei, Jingshen Cao, Weijia Wang, Huiqing Fan

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Benzene ring-doped graphitic carbon nitride (BD–CN) is constructed by one-step thermal polymerization for boosting photocatalytic hydrogen evolution and pollutant degradation performance. The increased photocatalytic activity is assigned to the grafting of aromatic benzene ring into the end of the heptazine polymer chains, which promotes photoinduced electron–hole pairs separation and charge transfer properties.

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原文链接:https://doi.org/10.1002/cssc.202500462

ChemistryEurope

1

Engineering Plasmonic Reactors for Co2 Reduction: from Nanoscale Catalysts to Novel Reactors

作者:Qiushi Wang, Ping Li, Hao Yang, Yexiang Tong

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This mini review highlights the critical role of reactor design in advancing plasmonic CO2reduction technologies. It emphasizes the need to integrate optimized reactors with LSPR materials to enhance catalytic efficiency, light absorption, and hot-carrier generation. Overcoming challenges in scalability, stability, and product separation.

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原文链接:https://doi.org/10.1002/ceur.202500087

2

Defect-Anchored Iridium Single Atoms on Palladium Metallenes for Synergistically Enhanced Ethanol Oxidation Reaction

作者:Wenbo Li, Mengyue Gao, Zhen Jiang, Cheng Han, Yanyan Jia, Kuan-Wen Wang, Sheng Dai

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This work presents a defect-site activation strategy, in which anchoring Ir single atoms onto the highly strained defects of Pd metallene generates synergistic Pd-Ir sites, leading to a dramatic enhancement in the ethanol oxidation reaction.

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原文链接:https://doi.org/10.1002/ceur.202500379

3

A Poly (β-Amino Esters)-Based Multicomponent Nanoparticle for Efficient mRNA Delivery to Acute Myeloid Leukemia Cells

作者:Zheng Wang, Dehua Huang, Lanrong Wu, Yuheng Cao, Yejun Zhang, Chunyan Li, Jiang Jiang, Guangcun Chen, Qiangbin Wang

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A structurally engineered nonviral vector (poly (β-amino esters)-lipid-palmitic anhydride nanoparticles) integrates a poly(β-amino ester) core for mRNA binding, palmitic anhydride for enhancing cellular uptake, and cationic 1,2-Dioleoyl-3-trimethylammonium-propane lipid for endosomal disruption is developed, which achieves 64.4% transfection efficiency in acute myeloid leukemia (AML) cells (MOLM13) with minimal toxicity, showcasing a versatile platform for AML research and mRNA-based therapeutics.

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原文链接:https://doi.org/10.1002/ceur.202500130

4

Radical-Mediated Sulfonylarylation of Unactivated Alkynes via Intramolecular 1,4-(hetero)aryl Migration

作者:Xu Zhang, Fushan Chen, Chen Zhu

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A photoredox neutral sulfonylarylation of unactivated alkynes is achieved through a radical-mediated intramolecular 1,4-(hetero)aryl migration. The product configuration can be controlled under the irradiation of blue or green light. The method features mild, transition metal-free conditions, good compatibility of functional groups, and high levels of regio- and stereoselectivity in the product formation.

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原文链接:https://doi.org/10.1002/ceur.202500121

5

Application of Metal-Organic Framework Composites

作者:Yihao Chen, Hengyue Xu, Jiakang Shi, Yichun Su, Xudong Chen, Huan Pang

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This review summarizes the applications of MOF composites in adsorption, energy storage, catalysis, biomedicine, and sensing. It also discusses the functionality of MOF composites from a dimensional perspective.

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原文链接:https://doi.org/10.1002/ceur.202500078

ChemElectroChem

1

Synergistic Additives Design for High-Voltage and Broad-Temperature Propylene Carbonate-Based Electrolytes in Practical Lithium-Ion Batteries

作者:Qijun Liu, Changjun Tuo, Mingsheng Qin, Jun Yang, Ziqi Zeng, Shijie Cheng, Jia Xie

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Hexafluorobenzene (HFB) enhances graphite compatibility in PC-based electrolytes by improving interfacial desolvation, while fluoroethylene carbonate (FEC) decomposes first, protecting HFB and ensuring stability. This dual-additive system enables wide-temperature performance, longevity, and high-voltage capability in NCM811/graphite cells.

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原文链接:https://doi.org/10.1002/celc.202500020

2

ZIF67-Derived Carbon@SiO2 Anode Materials for Lithium Ion Batteries: Preparation, Characterization, and Performance

作者:Lulu Yan, Xiaoya Mu, Jun Ma, Shuo Geng, Fan Yang

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A ZIF67-derived carbon/silicon dioxide (ZIF67-C@SiO2) composite was synthesized via in situ coating to address volume expansion and capacity fading in lithium-ion batteries (LIBs). The porous, N-doped carbon framework improves lithium-ion diffusion and buffers SiO2 expansion, delivering a high reversible capacity of 849.7 mAh·g−1 and excellent cycling stability.

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原文链接:https://doi.org/10.1002/celc.202500167

3

Perovskite Oxides for Electrocatalytic Hydrogen/Oxygen Evolution Reaction

作者:Lu Lu, Mingzi Sun, Tong Wu, Qiuyang Lu, Baian Chen, Cheuk Hei Chan, Hon Ho Wong, Zikang Li, Bolong Huang

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To provide a comprehensive reference for the future design of highly active perovskite-oxide electrocatalysts from both the theoretical and experimental perspectives, the fundamental mechanisms of hydrogen evolution reaction (HER) and oxygen evolution reaction (OER), synthetic methods, recently reported perovskite-oxide electrocatalysts and effective tuning strategies have been fully discussed in this review.

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原文链接:https://doi.org/10.1002/celc.202400648

4

Alloy Catalysts for Electrochemical Nitrate Reduction to Ammonia

作者:Rong Zhang, Xintao Ma, Shaoce Zhang, Qing Li, Yuwei Zhao, Chunyi Zhi

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This review systematically examines the recent advancements in alloy catalysts including bimetallic alloy, medium entropy alloy and high entropy alloy for electrochemical nitrate reduction to ammonia, comprehensively analyzing their structure, catalytic activity, and the mechanisms. Future prospects and challenges in electrochemical nitrate reduction are also discussed.

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原文链接:https://doi.org/10.1002/celc.202400499

5

In Situ Characterization of Competitive (De)Lithiation in Silicon/Graphite Composite Electrodes via Electrode Curvature Measurement

作者:Min Li, Huibing Liu, Yicheng Song, Bo Lu, Junqian Zhang

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An in-situ method for characterizing competitive (de)lithiation in silicon/graphite electrodes is developed in this paper. By utilizing electrode curvature measurements and establishing the curvature capacity relationship, the capacity evolution of individual components is quantified. Distinct competitive (de)lithiation stages are revealed. This method provides a new perspective for analyzing electrochemical processes within multiphase active material systems.

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原文链接:https://doi.org/10.1002/celc.202400614

ChemistryOpen

1

Progress in Aptamer Research and Future Applications

作者:Song Liu, Xiaolu Li, Huyang Gao, Jing Chen, Hongfeng Jiang

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This paper mainly describes the screening method of aptamer, the screening difficulties and improvement methods of small molecule aptamer, and the application and treatment of aptamer. It explores the latest progress and application of aptamers, and summarises them, thus indicating some problems that still exist in this field.

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原文链接:https://doi.org/10.1002/open.202400463

2

Advances in Molecularly Imprinted Polymers for Bone Biomarker Detection and Therapeutic Applications

作者:Ren Yang, Xiaohan Ma, Mingcheng Xuan, Yingqi Ma, Jiexian Ding, David Y. S. Chau, Jonathan C. Knowles, Feng Peng, Alessandro Poma

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This review highlights the emerging applications of molecularly imprinted polymers (MIPs) in bone regeneration and diagnosis. MIPs facilitate osteogenic treatments by guiding stem cell differentiation and delivering bioactive molecules and enable precise detection of bone turnover biomarkers via MIP-based sensors, offering promising strategies for next-generation bone repair and monitoring.

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原文链接:https://doi.org/10.1002/open.202500127

3

Preparation of P-Doped Ni Catalyst Using Deep Eutectic Solvents and Its Excellent Hydrogen Evolution Performance in Water Splitting

作者:Chenyun Zhang, Jiahao Wang

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A deep eutectic solvent (DES) prepared by mixing tetraalkylphosphonium chloride ([P4444]Cl) and glycerol is applied in the synthesis of P-doped Ni materials. The DES not only serves as the reaction medium but also participates in the catalyst preparation. The synthesized P-doped Ni catalyst exhibits excellent performance in HER in both acidic and alkaline environments.

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原文链接:https://doi.org/10.1002/open.202500023

4

Three-Component 1,2-Methylamidation of Alkynes via Coordinating Activation Strategy

作者:Jing Ren, Kaiyun Liu, Ning Wang, Jinlong Li, Xinyu Long, Chengming Li, Kaizhi Li

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A copper-catalyzed three-component 1,2-methylamidation of alkynes utilizing a novel coordinating activation strategy has been successfully developed.

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原文链接:https://doi.org/10.1002/open.202500151

5

Development of an Integrated Computational Pipeline for PARP-1 Inhibitor Screening Using Hybrid Virtual Screening and Molecular Dynamics Simulations

作者:Guan Wang, Jingjing Guo, Feng Xu, Mingjuan Ji

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Poly(ADP-ribose) polymerase 1 (PARP-1) is vital for DNA repair. A computational workflow integrating AI-driven virtual screening (TransFoxMol, KarmaDock, AutoDock Vina) and molecular dynamics identified novel PARP-1 inhibitors with promising efficacy and minimized side effects. Our approach offers systematic insights for advancing precision oncology drug discovery and clinical research.

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原文链接:https://doi.org/10.1002/open.202500021

Chemistry-Methods

1

Modification Strategies for Enhancing the Performance of Lithium Manganese Iron Phosphate Cathodes in Lithium-Ion Batteries

作者:Zijian Qiu, Quanyan Man, Yongbiao Mu, Huicun Gu, Zhiyu Zou, Meisheng Han, Lin Zeng

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This review focuses on the structure and performance of lithium manganese iron phosphate (LMFP), a potential cathode material for the next-generation lithium-ion batteries (LIBs). How modifications like exotic element doping, surface coating, and material nanostructuring enhance its electrochemical properties are studied. The insights provide an aim to accelerate the development of high-performance, cost-effective LMFP cathode materials for advanced lithium-ion battery technology.

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原文链接:https://doi.org/10.1002/cmtd.202400065

2

Carbonylative Transformations of Aryl Sulfonium Salts

作者:Yan-Hua Zhao, Xiao-Feng Wu

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Carbonyl derivatives are widely present in biologically active molecules, pharmaceuticals, natural products, and materials, and their synthesis has garnered much attention. Direct carbonylation of aromatic C-H bonds is an effective tool for the synthesis of carbonyl compounds. In this review, the recent advances in the site-selective carbonylation transformation of arenes via aryl sulfonium salts, as well as their reaction mechanisms and synthetic applications are summarized and discussed systematically.

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原文链接:https://doi.org/10.1002/cmtd.202500089

3

Exploring Bonding in Bioinorganic Chemistry: Ab Initio Valence Bond Calculations of Iron(II)-CO and Iron(IV)-Oxo Units in Cytochrome P450 under Oriented External Electric Fields

作者:Enhua Zhang, Hajime Hirao

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Ab initio valence bond calculations under oriented electric fields along the bond axis of Fe(II)-CO and Fe(IV)-oxo units in cytochrome P450 enzymes highlight their effectiveness in probing complex bonding characteristics and ligand effects in bioinorganic systems.

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原文链接:https://doi.org/10.1002/cmtd.202400090

4

Charge-Assisted Hydrogen-Bonded Organic Frameworks: From Crystal Engineering to Multifunctional Materials

作者:Xian-Xian Xiao, Kai Zheng, Hao-Ran Yu, Fang-Di Dong, Ding-Yi Hu, Rui-Biao Lin

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This review briefly highlights the construction of charge-assisted hydrogen-bonded organic frameworks using a variety of organic acids and organic bases, which feature different hydrogen-bonding motifs, along with their applications, including negative linear compressibility, proton conduction, atmospheric water harvesting, gas adsorption and separation, molecular rotors, optical properties, and biological applications.

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原文链接:https://doi.org/10.1002/cmtd.202400082

5

Multilayered MXene/Pristine Carbon/Biomass Cellulose Film Electrode with Ultrahigh Volumetric Capacitance for Symmetric Flexible Supercapacitor

作者:Lina Liu, Shuai Yan, Lingyan Huang, Jiangang Wang, Qiaoyu Zhang, Shiyun Li, Jie Liu, Xuecheng Chen

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Multilayered sandwich-structured MXene/pristine carbon/biomass cellulose composite films have been constructed with a hierarchical network architecture. A symmetric flexible soft-pack supercapacitor fabricated by using the film retains 98% of its initial capacitance after 10 000 cycles.

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原文链接:https://doi.org/10.1002/cmtd.202500036

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